Source: cinemablend.com

2. Baron Zemo

Are we talkin' about Baron Zemo? We talkin' about Helmut Zemo of the Zemo family? We talkin' about a founding Thunderbolt? Because Baron Zemo is so friggin' rad.

Helmut is the son of Heinrich Zemo, the first Baron Zemo to fight Captain America. That Baron Zemo is best known for accidentally gluing his own mask to his face. Real winner, that one. Real A-number one supervillain.

Helmut suffered a similar accident, but he wasn't wearing his mask at the time, so instead of getting his dumb pink hood glued to his flesh, he just had his face melted. Helmut would later found an incarnation of the Masters of Evil and form the Thunderbolts, aka my favorite superhero team of all time, as Citizen V.

Although the T-bolts didn't become superheroes until after Zemo got booted for trying to conquer the earth. Just couldn't go straight, could ya Helmut? You melty-faced cretin, you.