Men in Black – Will Smith from Men in Black

Sure, it's not a "superhero" movie, which may skew the list a little. But a comic book movie is a comic book movie and Men In Black from the movie of the same title might just be the most well-known song on this list. Sampling "Forget Me Nots" from 1984, Smith released his first solo song (bye bye Jazzy Jeff) along with his blockbuster film with Tommy Lee Jones. The song won a Grammy and was burned into everyone's minds for weeks and months following the release of both the movie and the song. And here I think we've unveiled a bit of secret sauce. Just like “Hero” and “Kiss from a Rose”, “Men in Black” played in the movie's credits. Perhaps this is the spot for solid gold comic book movie songs.