Mickey Rourke

Mickey Rourke was introduced as Marv in Frank Miller’s 2005 flick, Sin City. He reprised his role in the 2014 sequel, Sin City: A Dame to Kill For.

In the second installment of the Iron Man film series, Rourke portrayed the supervillain Ivan Vanko, aka Whiplash.

Hugo Weaving

Hugo Weaving portrayed the anarchist freedom fighter named V in James McTeigue’s V for Vendetta. The movie was based on the Vertigo Comics limited series of the same name.

Hugo Weaving returned to the comic book movie genre in the MCU flick Captain America: The First Avenger. He played the supervillain Johann Schmidt, aka Red Skull, in that movie.